After scoring 711 runs with four centuries against the West Indies, Kallis pushed aside some indifferent form on the tour to date and scored 92 before hooking Jacob Oram to Daryl Tuffey on the backward square boundary 20 minutes from stumps.
It was one of the few rash shots that led to his downfall. He had been becalmed on 90 for 21 balls and appeared to be riding out the new ball danger when he fell, having faced 177 balls and hit 11 fours and three sixes.
At 79, Herschelle Gibbs, who had hit Vettori over long-on for six, illustrated the sluggish nature of the pitch when he attempted a back foot drive off Vettori. He was through the shot before the ball arrived and hit a hard catch to Styris at short cover.
Scorecard
South Africa 1st innings
G.Smith c Oram b Vettori 25
H.Gibbs c Styris b Vettori 40
J.Rudolph c McCullum b Styris 72
J.Kallis c Tuffey b Oram 92
G.Kirsten not out 31
P.Adams not out 7
Extras (nb-8, lb-3, b-1) 12
Total (for four wickets, 90 overs) 279
Fall of wickets: 1-51, 2-79, 3-211, 4-271.
Bowling: Tuffey 19-8-45-0 (nb-1), Oram 18-6-50-1, Vettori 23-2-83-2 (nb-1), Cairns 12-0-33-0 (nb-6), Wiseman 7-1-35-0, Styris 10-3-24-1, McMillan 1-0-5-0.
To bat: M.Boucher, S.Pollock, N.McKenzie, M.Ntini, A.Nel.